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Pyrolysis
Disclaimer: The Discover article below is Capitalist Propaganda. However what is being touted by the Capitalists is that any carbon based material can be converted to fuel and other byproducts There are a number of different methods offered, including producing solid fuel by microwaving, etc., Prolysis is one such method. Whatever the method, both the Capitalists 'and' the anti-Capitalists agree that such a technological 'direction' could supply much of the world's energy needs without fossil fuels. In such a world, 'no-thing' would go to 'waste.' ...Mars |
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DISCOVER Vol. 24 No. 5 (May 2003) Anything into Oil
In an industrial park in Philadelphia sits a new machine that can change
almost anything into oil.
But first things first. Today, here at the plant at Philadelphia's Naval Business Center, the experimental feedstock is turkey processing-plant waste: feathers, bones, skin, blood, fat, guts. A forklift dumps 1,400 pounds of the nasty stuff into the machine's first stage, a 350-horsepower grinder that masticates it into gray brown slurry. From there it flows into a series of tanks and pipes, which hum and hiss as they heat, digest, and break down the mixture. Two hours later, a white-jacketed technician turns a spigot. Out pours a honey-colored fluid, steaming a bit in the cold warehouse as it fills a glass beaker. It really is a lovely oil. "The longest carbon chains are C-18 or so," says Appel, admiring the liquid. "That's a very light oil. It is essentially the same as a mix of half fuel oil, half gasoline." Private investors, who have chipped in $40 million to develop the process, aren't the only ones who are impressed. The federal government has granted more than $12 million to push the work along. "We will be able to make oil for $8 to $12 a barrel," says Paul Baskis, the inventor of the process. "We are going to be able to switch to a carbohydrate economy." Making oil and gas from hydrocarbon-based waste is a trick that Earth
mastered long ago. Most crude oil comes from one-celled plants and animals
that die, settle to ocean floors, decompose, and are mashed by sliding
tectonic plates, a process geologists call subduction. Under pressure
and heat, the dead creatures' long chains of hydrogen, oxygen, and carbon-bearing
molecules, known as polymers, decompose into short-chain petroleum hydrocarbons.
However, Earth takes its own sweet time doing this—generally thousands
or millions of years—because subterranean heat and pressure changes are
chaotic. Thermal depolymerization machines turbocharge the process by
precisely raising heat and pressure to levels that break the feedstock's
long molecular bonds.
Experimentation revealed that different waste streams require different cooking and coking times and yield different finished products. "It's a two-step process, and you do more in step one or step two depending on what you are processing," Terry Adams says. "With the turkey guts, you do the lion's share in the first stage. With mixed plastics, most of the breakdown happens in the second stage." The oil-to-mineral ratios vary too. Plastic bottles, for example, yield copious amounts of oil, while tires yield more minerals and other solids. So far, says Adams, "nothing hazardous comes out from any feedstock we try." "The only thing this process can't handle is nuclear waste," Appel says. "If it contains carbon, we can do it." à This Philadelphia pilot plant can handle only seven tons of waste a day, but 1,054 miles to the west, in Carthage, Missouri, about 100 yards from one of ConAgra Foods' massive Butterball Turkey plants, sits the company's first commercial-scale thermal depolymerization plant. The $20 million facility, scheduled to go online any day, is expected to digest more than 200 tons of turkey-processing waste every 24 hours. The north side of Carthage smells like Thanksgiving all the time. At
the Butterball plant, workers slaughter, pluck, parcook, and package 30,000
turkeys each workday, filling the air with the distinctive tang of boiling
bird. A factory tour reveals the grisly realities of large-scale poultry
processing. Inside, an endless chain of hanging carcasses clanks past
knife-wielding laborers who slash away. Outside, a tanker truck idles,
full to the top with fresh turkey blood. For many years, ConAgra Foods
has trucked the plant's waste—feathers, organs, and other nonusable parts—to
a rendering facility where it was ground and dried to make animal feed,
fertilizer, and other chemical products. But bovine spongiform encephalopathy,
also known as mad cow disease, can spread among cattle from recycled feed,
and although no similar disease has been found in poultry, regulators
are becoming skittish about feeding animals to animals. In Europe the
practice is illegal for all livestock. Since 1997, the United States has
prohibited the feeding of most recycled animal waste to cattle. Ultimately,
the specter of European-style mad-cow regulations may kick-start the acceptance
of thermal depolymerization. "In Europe, there are mountains of bones
piling up," says Alf Andreassen. "When recycling waste into feed stops
in this country, it will change everything."
Chemistry, not alchemy, turns (A) turkey offal—guts, skin, bones, fat, blood, and feathers—into a variety of useful products. After the first-stage heat-and-pressure reaction, fats, proteins, and carbohydrates break down into (B) carboxylic oil, which is composed of fatty acids, carbohydrates, and amino acids. The second-stage reaction strips off the fatty acids' carboxyl group (a carbon atom, two oxygen atoms, and a hydrogen atom) and breaks the remaining hydrocarbon chains into smaller fragments, yielding (C) a light oil. This oil can be used as is, or further distilled (using a larger version of the bench-top distiller in the background) into lighter fuels such as (D) naphtha, (E) gasoline, and (F) kerosene. The process also yields (G) fertilizer-grade minerals derived mostly from bones and (H) industrially useful carbon black. Garbage In, Oil Out Feedstock is funneled into a grinder and mixed with water to create a
slurry that is pumped into the first-stage reactor, where heat and pressure
partially break apart long molecular chains. The resulting organic soup
flows into a flash vessel where pressure drops dramatically, liberating
some of the water, which returns back upstream to preheat the flow into
the first-stage reactor. In the second-stage reactor, the remaining organic
material is subjected to more intense heat, continuing the breakup of
molecular chains. The resulting hot vapor then goes into vertical distillation
tanks, which separate it into gases, light oils, heavy oils, water, and
solid carbon. The gases are burned on-site to make heat to power the process,
and the water, which is pathogen free, goes to a municipal waste plant.
The oils and carbon are deposited in storage tanks, ready for sale.
A Boon to Oil and Coal Companies One might expect fossil-fuel companies to fight thermal depolymerization.
If the process can make oil out of waste, why would anyone bother to get
it out of the ground? But switching to an energy economy based entirely
on reformed waste will be a long process, requiring the construction of
thousands of thermal depolymerization plants. In the meantime, thermal
depolymerization can make the petroleum industry itself cleaner and more
profitable, says John Riordan, president and CEO of the Gas Technology
Institute, an industry research organization. Experiments at the Philadelphia
thermal depolymerization plant have converted heavy crude oil, shale,
and tar sands into light oils, gases, and graphite-type carbon. "When
you refine petroleum, you end up with a heavy solid-waste product that's
a big problem," Riordan says. "This technology will convert these waste
materials into natural gas, oil, and carbon. It will fit right into the
existing infrastructure." Can Thermal Depolymerization Slow Global Warming? If the thermal depolymerization process WORKS AS Claimed, it will clean
up waste and generate new sources of energy. But its backers contend it
could also stem global warming, which sounds iffy. After all, burning
oil creates global warming, doesn't it?
RELATED WEB SITES: To learn more about the thermal depolymerization process, visit Changing World Technologies' Web site: http://www.changingworldtech.com/. A primer on the natural carbon cycle can be found at www.whrc.org/science/carbon/carbon.htm.
The Walt Disney Company. |
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BioPower for America |
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| BioPower capitalizes on what has always been one of America’s strengths: its highly productive farmland and forests. Today, power production from plant material supports 66,000 jobs, and accounts for about one percent of all of America’s electricity production. In the near future, integrated factories will use biomass to produce a combination of electricity, food, feed, fuels, and a wide range of industrial materials. | |||||||||||||||
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BioPower is good for America.
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The DOE BioPower Program supports technology development in the following areas: |
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Cofiring in existing power stations involves firing up to 20% biomass in a coal-fired boiler. This reduces air pollution (SOx, NOx) and lowers fuel costs. In cooperation with the Electric Power Research Institute, the research and development organization of the U.S. electric power industry, several on-site test programs are now underway in Indiana, Tennessee, New York and Pennsylvania. [Click here to learn more…] Biomass gasification converts solid plant material into a rich gaseous fuel, which allows it to be used in high efficiency gas turbine plant and fuel cells. Today, most new power plants are natural gas-fired turbine systems because they are relatively cheap to build and operate. Field tests in Burlington, Vermont are nearing completion while commercial applications are being actively pursued. [Click here to learn more…] Small, modular biomass power systems are being developed for distributed power applications. Distributed power systems are especially attractive for developing countries that have limited central power grids. This technology is an excellent opportunity for U.S. companies in the export market. [Click here to learn more…] |
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Feedstock development activities are "planting the seeds" for an integrated energy crop industry. Fast growing wood and grass varieties are mechanically planted and harvested as an alternative crop. The farming techniques that will make energy crops cost-competitive and provide a new market for the rural economy are beginning to be demonstrated in the U.S. Through the DOE/USDA Biomass Power for Rural Development Program, cofiring projects for energy crops are underway in Alabama, Iowa, and New York. [Click here to learn more…]
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Our
Product Range
Our fuel is not bio-diesel in the form of Rapeseed Methyl Ester (RME), which in our view is not a very 'green' form of bio-fuel. Our form of fuel is more akin to Straight vegetable fat, but it can be burned in normal compression ignition engines just like normal mineral diesel. Like all non-fossil fuels, it does not pollute the atmosphere nor add to the causes of global warming. The type of fuel is called 'Modified Waste Vegetable Fat' (MWVF), and our product for use as a road fuel is called 'bio-power V100'. We also make a high energy fuel for heating and electricity generation which we call 'bio-power G100'. A full description of our products is available at Our Product Range. The full story of how we originally got involved in this business is told at How it all began. How best to use this
web site The bio-power Charter About the Bio-power
company and the Bio-power network Our Product
Range Frequently Asked
Questions (FAQ) If you are researching in to bio-fuels or the making of bio-diesel (which we no longer make), then all the technical stuff published on our old web site is here, including a description of the Basic Chemistry of Bio-fuels, and a Glossary of all technical Terms. There also is a section explaining how to make a simple form of our fuel which you can test in your own engine, and how to build a simple heat exchanger following our design to improve the performance of any engine. Taxation Our vision for a
bio-power network. Invest in us Quotes Links
Download Letters and
correspondence
Bio-power (uk) and John Nicholson do not accept any responsibility for loss occasioned to any person acting or refraining from action in reliance on or as a result of the material included in or omitted from this web site, or its officers or trustees or employees or any other persons. © is held by John Nicholson 2002. All rights are reserved. No part of the information published on this web site may be reproduced or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, or stored in any retrieval system of any nature without prior written permission of the copyright holder except as expressly permitted by law.
John Nicholson |
| Adaptable 55 gallon Batch Processor | |||||||
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| Specs: -55 gallon batch size, 125 gallon total capacity, stainless steel tank -20 gpm magnetic drive Ryton centrifugal pump for mixing -PEX plumbed mixing circuit -Variable Catalyst/ Alcohol Injection rate capablity -35 element stainless steel static mixer -Closed loop hydronic recirculation heating system -Combination Closed loop mist washing and bubble washing systems - Water cooled alcohol condensor Future additions -PLC process control for automated operation -15 micron final filter/ water seperation system. -Glycerine post-processing system for alcohol recovery |
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| Special Thanks: This processor is to be used for educational and research purposes at Purdue University. I would like to thank the many members of the biodiesel discussion forum who helped with the design of this processor. |
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http://www.goatindustries.fsnet.co.uk/svoreport.htm Background. As oil and gas reserves gradually dwindle and global warming due to CO2 emissions becomes more obvious we are going to need to consider alternative fuels, especially where road transport is concerned. Electricity and heat generation can be more easily catered for by large, static power generation schemes such as wind farms and hydro power. We may well find that we will be dependent on liquid hydrocarbon fuel for many years to come. This is mostly due to the technical problems associated with compact, lightweight, fast moving vehicles that need to cover large distances with minimum interruption. Engines burning liquids and compressed gases conform to these criterion as their fuel tanks are relatively small and the calorific value of the fuels relatively large. Much research has been done to investigate the use of organic oils as a road transport fuel and key environmental and mechanical factors have been clearly identified. The obvious carbon cycle related advantages of organic oils have been examined, although we should remember that animal oil production is much less important than plant oil in this respect. Animal oils should be considered as waste product from the meat industry rather than a 'primary' product. Vegetable oil bearing crops, on the other hand, can be grown specifically for fuel production and it is important that the negative aspects of these crops and their usage does not outweigh the positive effects on global warming. Effects on biodiversity, air pollution, water pollution, land usage, engine wear, engine reliability, energy usage in manufacture, stability of the fuel, bio-degradability have already been extensively researched by the academic institutions and we are at a point where these bio-fuels can be used in road going vehicles with minimal damage to the environment. There is also a large amount of waste vegetable oil that can be easily filtered and used directly as a fuel. Straight vegetable oil (SVO) as a fuel can be compared with organic oil methyl esters (ME's) and there are many studies that have done this. The main points of contention seem to be that neat oil could produce more damage to engines and more harmful emissions than processed oil, but the reports seem to differ widely in their findings. Some say there are more harmful emissions than methyl ester and fossil diesel, some say there is less. There are many engine modifications that can be made to make SVO more acceptable, such as pre-heating the fuel or changing the ignition timing, but the greatest factor seems to be the actual mechanical and thermodynamic nature of the individual engines themselves. It would be thus sensible to assume that some vehicles are likely to be more suitable for SVO and others for ME's. In all cases it seems that, if SVO is to be used, it should be used in combination with another fuel of lower viscosity such as ME and the fuels should either be mixed together or the ME be used to cold start the vehicle and then switch over to SVO when the engine reaches optimum operational temperature. SVO has many advantages over ME in terms of energy usage and pollution and fuel stability. ME requires additional processing other than that associated with refining the organic oil it is derived from. Many ME processes require chemicals such as methanol and sulphuric acid which are generally derived from non-renewable sources. The process itself requires energy to heat and mix the chemicals and large-scale industrial plant for cost effectiveness, there are also polluting byproducts in the refining stage1 such as large quantities of dirty water which are generally discarded rather than eliminated. The health and safety and environmental aspects of producing ME generally mean that it can only be produced in relatively few large plants, which has important social/economic considerations. There are additional transport costs in transporting the fuel from the fields to the factory, and then back to the end user and such centralized industry has adverse effects on local communities by taking the jobs and wealth out of the local area.
References
DTLR
GUIDANCE ON ENVIRONMENTAL CRITERIA
Air quality: emissions of local pollutants · 1,3 butadiene (CH2CHCHCH2) · carbon monoxide (CO) · lead (Pb) · nitrogen dioxide (NO2) · ozone (O3)
· particulates (PM10) · sulphur dioxide (SO2) Climate change: emissions of greenhouse gases · methane (CH4) · nitrous oxide (N2O) · hydroflourocarbons (HFCs) · perflourocarbons (PFCs) · sulphur hexaflouride (SF6) The Government also has a domestic goal of reducing CO2 emissions by 20 per cent below 1990 levels by 2010. Climate Change – The UK Programme, published in November 2000, set out the policies the Government was putting in place to meet the Kyoto agreement and move towards our domestic goal.
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Hi Volks! Mike Fritz wrote: > I think the point being made was one can use McDonalds oil. I'm sure it would > have to be refined to some point. The news report on the local cement trucks > using it said the exhaust smells like a McDonalds restaurant. The fuel in this > case is bought from a station that sells biodiesel, they get it from some sort of > plant, I forget though, no McDonalds. Exactly. Bio Diesel is not re-cycled frying oil. It's cheaper than regular Diesel in Europe because there's no tax on it, and it isn't *way* cheaper because they couldn't make it as fast as they could sell it if it were. Thus, they always stay some 10 cents per liter under the price of Dino Diesel, and with the continually rising tax on that, they presumably make obscene amounts of money on it. Works just like the real thing, but smells like french fries allright. However, older Diesel engines do run on vegetable oil, the kind you buy in the supermarket to pour into salads or fry eggs in. That stuff is lots cheaper than Bio Diesel, but you'll notice a power loss and a certain unwillingness to start up in the mornings. Several pals of mine drive that way. It works. (They drive old junkheaps, in case you wondered. I sure wouldn't use it in anything that said "TDI" on the decklid.) The real nuts drive on re-cycled frying oil, filtered and heated so as to flow. That's virtually free fuel, but a lot of modifications and refining machinery in the garage are needed to pull this off. I only read about these. ...... Airhowlingly yours, Erik.
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Sir John Houghton's
scientific assessment of the effect of Global warming and
climate Change, how it is caused, UK
Survival in the 21st Century The Busby Report: A national
plan for survival in the 21st Century Links to other sites about bio-fuels Bio-power web based community
join this community to keep in contact with The Vegiepower UK information board developed by Simon Wells Ebony
Solutions commercial maker of e-diesel in UK. Will
deliver in 1,000 litre The Maui Bulletin Board the largest resource used by bio-fuel makers, large and small The Journey to forever a site full of information about better ways of doing things Dieselveg
a new compnay in Wolverhampton who can supply or fit
conversion kits to enable Biofuel
Systems Ltd Ormskirk, Cheshire. Company that can
provide ready made equipment Yellow
Bio-diesel this must be the best presented of all sites
on making bio-diesel
Goat
Industries A grand name for one remarkable person, Paddy
Whetman, who started Terry de Winne's characteristically
uncompromising campaign for simpler UK taxation of bio-fuels, The British Association of Bio Fuels and Oils (BABFO) what do they do? The Veggie van project in USA the story of the veggievan Biodiesel discussion board a USA based forum with some sections for UK National Biodiesel Board fact sheet and information of all kinds Steve Spence loads of information on all kinds of environmental and sustainability matters World energy solutions pure and simple. Makers of envirodiesel in USA Canadian Renewable Fuels Association Neoteric Biofuels Inc. Canadian company that produces bio-diesel, and SVO kits Fat of the Land process on the road film from USA and the recipe they used TabyPressen Swedish commercial processor, and bulletin board
Bio-diesel Bulletin Board run by national Biodiesel Board in USA Veg-Oil-Car.com Ian Tansley's site to promote the use of straight vegetable fat. Veg-Oil-Car.com
forum Discuss the advantages and disadvantages of runing
your car
LINKS TO OTHER SITES about other alternative fuel sources :- Ethanol Robert Warren's
site explains how to make ethanol form organic materials Grease
car .com A site that specialises on the use of SVO and
conversions. Centre
for Implosion Research They make and distribute the
Bio-power range of fuel line heat exchangers, LILI .Low Impact
Living Initiative Community run courses on all aspects
of Gwynedd21 a visionary impulse
to facilitate the furtherance of sustainability by Point
fusion news and information promoting sustainable transport
initiatives, Bio-diesel Filling Stations
A list of places where you can buy bio-fuels in the UK |
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